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Infrared Spectroscopy for the MCAT: Functional Group Peaks Table
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IR spectroscopy shows which bonds are present. Bonds absorb at characteristic wavenumbers (cm-1). On the MCAT you mainly need a few strong peaks and their shapes.
Peaks to memorize
| Bond | Wavenumber (cm-1) | Shape and notes |
|---|---|---|
| O-H (alcohol) | about 3200 to 3600 | Broad, strong |
| O-H (carboxylic acid) | about 2500 to 3300 | Very broad, overlaps C-H |
| N-H | about 3300 to 3500 | Sharper than O-H; primary amines show two peaks, secondary one |
| C-H (sp3) | just under 3000 | Alkane C-H |
| C-H (sp2) | just over 3000 | Alkene and aromatic C-H |
| C triple bond C or C triple bond N | about 2100 to 2260 | Sharp, in a quiet region |
| C=O | about 1650 to 1750 | Strong, sharp, the easiest peak to spot |
| C=C | about 1600 to 1680 | Weaker than C=O |
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A fast routine
- Look near 1700 for a strong C=O.
- Look above 3200 for an O-H or N-H.
- Combine them: C=O plus a very broad O-H is a carboxylic acid; C=O with no O-H or N-H is a ketone, aldehyde or ester; a broad O-H with no C=O is an alcohol.
- Check for an aldehyde C-H near 2700 to 2850 (two small peaks).
Common traps
- Mixing alcohol and acid O-H. The acid O-H is wider and extends lower.
- Missing conjugation. A conjugated C=O absorbs at a slightly lower wavenumber.
- Reading only the fingerprint region. Below about 1500 it is too complex for the MCAT.
- Expecting an amide to look like a ketone. Amide C=O sits lower, around 1650.
One-minute recap
- C=O: strong, sharp, near 1700.
- O-H: broad above 3200; acid is very broad.
- Triple bonds: near 2100 to 2260.
Check yourself: 5-question mini-quiz
1. Where does a carbonyl C=O absorb?
Near 1700 cm-1, strong and sharp.
2. How does a carboxylic acid O-H differ from an alcohol O-H?
It is much broader and extends lower, about 2500 to 3300.
3. Where do alkyne and nitrile triple bonds absorb?
About 2100 to 2260 cm-1.
4. What distinguishes a primary amine N-H in IR?
Two peaks near 3300 to 3500.
5. Why is the fingerprint region not used on the MCAT?
It is too complex to assign.
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Keep studying
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- All free notes
Check your email
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Download your free sample: 3-page Amino Acids, Proteins and Enzymes cheat sheet (PDF)
Meanwhile, start with the free notes.